Atomic number
33
Atomic mass
74.9216 g.mol -1
Electronegativity according to Pauling
2.0
Density
5.7 g.cm-3 at 14°C
Melting point
814 °C (36 atm)
Boiling point
615 °C (sublimation)
Arsenic appears in three allotropic forms: yellow, black and grey; the stable form is a silver-gray, brittle crystalline solid. It tarnishes rapidly in air, and at high temperatures burns forming a white cloud of arsenic trioxide. Arsenic is a member of group Va of the periodic table, which combines readily with many elements.
The metallic form is brittle, tharnishes and when heated it rapidly oxidizes to arsenic trioxide, which has a garlic odor. The non metallic form is less reactive but will dissolve when heated with strong oxidizing acids and alkalis.
Arsenic can be found naturally on earth in small concentrations. It occurs in soil and minerals and it may enter air, water and land through wind-blown dust and water run-off. Arsenic in the atmosphere comes from various sources: vulcanoes release about 3000 tonnes per year and microorganisms release volatile methylarsines to the extent of 20.000 tonnes per year, but human activity is responsible for much more: 80.000 tonnes of arsenic per year are released by the burning of fossil fuels.
Arsenic is one of the most toxic elements that can be found. Despite their toxic effect, inorganic arsenic bonds occur on earth naturally in small amounts. Humans may be exposed to arsenic through food, water and air. Exposure may also occur through skin contact with soil or water that contains arsenic.
Levels of arsenic in food are fairly low, as it is not added due to its toxicity. But levels of arsenic in fish and seafood may be high, because fish absorb arsenic from the water they live in. Luckily this is mainly the fairly harmless organic form of arsenic, but fish that contain significant amounts of inorganic arsenic may be a danger to human health.
The arsenic cycle has broadened as a consequence of human interference and due to this, large amounts of arsenic end up in the environment and in living organisms. Arsenic is mainly emitted by the copper producing industries, but also during lead and zinc production and in agriculture. It cannot be destroyed once it has entered the environment, so that the amounts that we add can spread and cause health effects to humans and animals on many locations on earth.
Plants absorb arsenic fairly easily, so that high-ranking concentrations may be present in food. The concentrations of the dangerous inorganic arsenics that are currently present in surface waters enhance the chances of alteration of genetic materials of fish. This is mainly caused by accumulation of arsenic in the bodies of plant-eating freshwater organisms. Birds eat the fish that already contain eminent amounts of arsenic and will die as a result of arsenic poisoning as the fish is decomposed in their bodies.
www.webelements.com/arsenic/
http://periodic.lanl.gov/elements/33.html
http://mineral.galleries.com/minerals/elements/arsenic/arsenic.htm